Beating a character's story mode would unlock their deck recipes and deck edit option in the free duel mode.
Deck | How to unlock
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Alito's deck recipe | Beat Alito's story.
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Astral's deck recipe | Beat Astral's story.
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Deck recipe and deck edit for other characters | Beat Konami-kun's story.
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Dr. Faker's deck recipe | Beat Dr. Faker's story.
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Kite's deck recipe | Beat Kite's story.
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Quattro's deck recipe | Beat Quattro's story.
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Shark's deck recipe | Beat Shark's story.
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Tori's deck recipe | Beat Tori's story.
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Trey's deck recipe | Beat Trey's story.
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Vetrix's deck recipe | Beat Vetrix's story.
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Yuma's deck recipe | Beat Yuma's story.
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Zexal's deck recipe | Beat Zexal's story.
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