| Character | How to unlock |
| Fight as Adelheid | Defeat Adelheid in Arcade mode.
|
| Fight as Ex Kyo Kusanagi | Successfully complete Challenge #30
|
| Fight as Gai | Defeat Gai in Arcade mode.
|
| Fight as Geese Howard | Successfully complete Challenge #40.
|
| Fight as Hotaru Futaba | Successfully complete Challenge #15.
|
| Fight as Jyazu | Defeat Jyazu in Arcade mode.
|
| Fight as Magaki | Successfully complete Challenge #6.
|
| Fight as Mai Shiranui | Successfully complete Challenge #20.
|
| Fight as Mr. Big | Successfully complete Challenge #35.
|
| Fight as Robert Garcia | Successfully complete Challenge #10.
|
| Fight as Shion | Defeat Shion in Arcade mode.
|
| Fight as Sho | Defeat Sho in Arcade mode.
|
| Fight as Silber | Defeat Silber in Arcade mode.
|
| Fight as Tung Fu Rue | Successfully complete Challenge #25.
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