| All Characters |
| Complete Asia Chapter with Kyo at level 10. Then highlight Chris at the character selection and press L1 + L2 + R1 + R2. All characters, including Orochi, will be selectable. |
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| Orochi |
| Hold L1 + L2 + R1 + R2 and select Chris at the character selection screen. |
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| Orochi Iori |
| Complete all chapters. Then hold L2 + R2 and select Iori at the character selection screen. |
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| Orochi Team |
| Complete all chapters. Then hold L2 + R2 and select all New Face Team members at the character selection screen. |
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| Saishu Kusanagi |
| Complete all chapters. Then hold L1 and select Kyo at the character selection screen. |
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| Sendo Siblings |
| Complete Disease Chapter. Then hold L2 + R2 and select any Art of Fighting team member at the character selection screen. |
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| Souiji Kusangai |
| Complete Souji and Aoi Chapters. Then hold L1 and select Kyo at the character selection screen. |
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